Yes and no.
Technically you can use it from newborn. Out of all of the 360 type seats available in about 2020, I found it the second best one for newborns (Besafe izi Turn or izi Twist is fantastic but quite a bit more expensive).
However, twins tend to be smaller than average and am I right in saying they are more likely to be premature? In this case you might not find it the best option. You have to be fairly confident in fitting babies into car seats to get a good fit for a newborn in this seat. The straps will absolutely drown them. The fit won't be good until probably about 4-6 weeks minimum. If they are smaller than average it might even be poor. The slope in your car can also make a big difference as to whether the angle is reclined enough for a newborn.
You may also want to consider whether you need a seat which can be removed from the car with the baby in it. I found this helpful when we had two children 3 years apart because it meant one of us didn't get stuck waiting in the car if the baby was asleep, and it was also handy for appointments where we had to navigate stairs, waiting rooms etc - I don't know if you tend to have more appointments for twins? Although it's not great to keep babies in car seats for long periods, it's very handy to have a portable sort of carrying thing that you can put down, click into a pushchair etc before the baby has the ability to stand on their own two feet. I didn't find it a big problem to stick to the recommended time limits as I just took the baby out for a cuddle when they woke up anyway.
If it's likely that you will drive them home from hospital and then very little until they are older, it might be a reasonable option but if you're likely to have a lot of driving with young babies it might make sense to look at either a fixed seat with a more supportive seating position, or a cheap infant carrier or a long lasting infant carrier so you can keep the benefit of the portable type seats for as long as possible and only change to the next stage when this is fully outgrown, at which point you don't then need a seat which is suitable from birth.
Supportive position fixed seat - Besafe izi Turn/Twist, Besafe Stretch, Avionaut Sky, Avionaut Stardust, Axkid One+ - all more expensive but some do last longer than the Joie 360 Spin.
Cheap infant carrier - Graco SnugLite seems to fit with universal pram adapters and is £70. Or Joie i-Juva/Hauck Comfort Fix are £50/60 (£100 with base) if you don't need pram compatability.
Long lasting infant carrier - Britax Baby-Safe Core / Avionaut Cosmo / Cybex Cloud.
Worth knowing also - the Graco Turn2me i-size is currently £129 in Halfords and is basically the same seat as the Joie 360 (Graco and Joie share a parent company) so you could save on that if you wanted to get something else initially and get the 360 seat for later.
You might want to also post in the multiples forum so you can get experiences from actual twin parents - I know about car seats, but not about the practicalities of parenting twins 