I struggled (and persevered) with breast feeding. Looking back, my breasts were rarely 'full' of milk (I was only sore a couple of times, and leaked once) and was feeding frequently and for a very long time each feed. DS was solely breast fed to 16 weeks, and kept pretty smoothly on the 9th centile line for weight.
I tried to pump, but failed miserably - I just never had a point when I was full of milk to make pumping easy to learn.
At 18 weeks I started to introduce formula in preparation for ds going to a childminder when I went back to work when he was 23 weeks. No sign of rejecting the bottle - he drank everything he was offered (which wasn't much until I actually went back to work). I then kept the breast feeding going night and morning, and during the day at weekends. Plus two formula feeds during the day. He shot up the weight curve over about 10 weeks from the 9th centile to the 75th. Then at about 8 months he firmly rejected all further offers of formula, his weight stabilised (stayed on the 75th centile) and we were back to solids plus breast feeds night and morning.
The local midwives and HVs were extremely supportive of breast feeding, but fairly ignorant of both the biology and the practicalities. They did their best, but there really wasn't any specialist help available locally. As an agricultural graduate (where you learn a fair amount about the biology of lactation) I found some of the advice I was given pretty suspect. Equally, my HV was rather startled when I told her that he had just demonstrated classic compensatory growth! (It was a real pain, because I had estimated his weight forward on the 9th centile to buy various bits of baby kit, and he promptly outgrew them in less than a month)
Ds eventually came off the breast around his second birthday, so I don't think I did too badly. It helped a lot that I was absolutely determined to bf, because of a family history of allergies. If I hadn't had that motivation, I am sure I would have given up pretty quickly.
So in answer to the Ops question, I suspect that the weight gain is down to quantity rather than quality. Provided the baby is not being pushed too hard she should settle down and her weight stabilise again.