I did this from when ds was about a week old, and I thought it was great!!!
I found expressing easy, luckily, and could express enough for a feed in one sitting, though not everyone can do this.
DS needed a feed at about 10 pm, so I used to express at about 9.30 pm, so DH could feed it straight away, as it was warm etc.
Then I could say a quick hello to ds at 10 pm, and then potter off for an early night, while DH and DS had some boy time.
I think it's really important for Dad's to get involved and have some time alone with the baby, so good for you and your DH for giving it a go.
I think it's also good to get a baby used to taking a bottle, to give to a bit of flexiblility later on.
I used an Avent Isis breast pump and normal Avent bottles, and never had any problem with my supply or nipple confusion.