Well, my pre-term DS was 3 weeks old and mostly tube fed when he started bottles. So I guess in theory it's possible, from the baby perspective.
BUT I don't know a single mother who has managed to express and bf a newborn. Seriously, when do you think you'll have time to express? As soon as your boobs are full after one feed your baby will want to empty them again. If you've expressed and you haven't got anything for your DC you are going to have one seriously pissed off baby on your hands.
The only scenario I can imagine it working is if you're expressing every day, at the same time, for DP to do the bottle shortly after. So, if at 3 months your DC is feeding at 7pm bed time and sleeping through for another feed at 11pm you could express at 9pm and get to bed, leaving DP to stay up (or get up) for 11pm feed. Then at least you've had a good sleep before the 1am-3am feed.
But, I honestly can't see how it would work with a 2 week old.
Also, if you're thinking about stocking up and the giving DC random bottles as and when, at different times and maybe more than one feed a day, tiktok is right, you could really mess up your supply.
I had a very scary episode when DS was in hospital. I was doing really well expressing, I had a stock in the freezer and had enough to give to my 2yr for her bedtime bottle. But then we had a really busy weekend and I let my expressing slip down from 5 times a day to 3 times a day. Buy the 3rd day I could only express 50mls, when I had been doing 250-300ml. I had to work really hard at building it back up again and actually I never did get my full supply back until DS came home.
Another point to make is that I think you're expecting too much. I promise that in those first two weeks you're not going to be thinking about expressing and bottles. You're going to be barely surviving!!
My honest advice would be to just get the first 2 months out of the way, then think about expressing so you can hand over a night feed.