I totally sympathise! I have the same problem, I also have neighbours who have a biomass boiler. Rural area - Move to the country for some fresh air they said! Mmm.
I can't hang my washing out, open our bathroom window after showering or kitchen windows when cooking. I can't open my child’s bedroom window to let cool air in in the summer. The environmental health dept at the council has been useless.
I bought a small PM2.5 monitor to measure the levels of pollution in the garden. Even when I informed the council of the really high readings I was picking up of around 180 they did nothing.
I also checked the PM2.5 readings in the house, as I could smell the smoke even with the windows closed, it gets in the flipping vents and everywhere doesn't it! The monitor showed me what my nose was telling me, that the PM2.5 levels were also raised within the house.
I now run a HEPA filter in the house, which is very effective at removing traces of the smoke and I can see the PM2.5 level on the monitor dropping after I’ve switched it on. This is, of course, not a long-term solution to the problem, but does mean I can at least keep the air clean in the house, and protect our health by not continuously breathing in the smoke fumes that seep in.
I say it's not a long-term solution, but it’s feeling like this is the best it’s going to get at this rate. I feel at a total loss to solve the issue, and it really gets me down at times. We have a lovely little garden and I’d love for my child to be able to play out there more, but our time in our garden is dictated by what’s coming out of the biomass boiler chimney.