I shall tell you the meaning of the symbols
Hazardous chemicals are classified according to their dangerous properies, i.e. flammable, toxic, corrosive, irritant.
Xi - substance is an irritant
Xn - substance is harmful
N - I think it means dangerous substance but can't remember!
The R codes are risk phrases which expand on the above classifications.
R43 - May cause sensitisation by skin contact
R10 - Flammable
R51/53 - Toxic to aquatic organism, may cause long term effects to the aquatic environment.
R65 - Repeated exposure may cause skin dryness or cracking.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
This will apply the the substance before it is used, i.e. in its liquid state. Once dry I would imagine most of the risks would be eliminated.
Can you prevent your littlies going into the back garden until the grout has completely dried out? The smell should dissipate soon I would have thought. Once the smell goes it'll be safe.
Oh and no I don't think yabu to be worried! But I think you'll find most grouts will have a similar composition.