I've always been interested in the disaster. The new programme on Sky Atlantic seems great so far.
The following is probably a bit boring for everyone, but ironically it was caused by running a safety test.
The reactors need continuous cooling, even after they have been shut down. Normally the cooling pumps were driven by the electricity generated by the power station itself, but if it stopped producing power, they were reliant on diesel generators to drive the cooling pumps instead. The safety test simulated a shut down to see how long the cooling pumps could continue to circulate the cooling water, until the diesel generators fired up.
The old Soviet reactors needed to be run at high power. At low power they were very unstable and, once run at low power for a length of time, it was extremely difficult to get the power to rise.
In the preparation for the test somebody made a mistake and dropped the power far too low, and they couldn't get it back up again.
So they completely removed all of the control rods (which are designed to keep the power levels under control, and also used to shut the reactor down in an emergency) to try to get the power up again.
They managed it, and started the test.
However, without any control rods, there was an unexpected power surge. They noticed it and frantically tried to get the control rods back in, but the control rods had a weird characteristic and design flaw, which meant as the tips were first inserted (after being completely removed), it led to an even bigger power surge.
This damaged the channels that the control rods need to move through, and they got jammed.
After that there was no way to control the reactor and the power went higher and higher, boiling off all of the coolant water, creating an enormous amount of steam pressure, until the whole roof of the reactor exploded into the air.