Joining thread slightly late.
We did this. The actual conversion was the most straightforward bit of it. The most complicated was the mortgaging.
Our original house was mortgaged. It was very difficult finding a lender who would let us get a mortgage for the second property. If I remember correctly, we had to get both mortgages from a single lender. Our original lender wouldn't go for it, and we needed the equity in our existing house to be able to afford the second house, so we needed both mortgages to be with the same lender, i.e. remortgage our first house and get a second mortgage for the second house, IYSWIM?
Part of the problem was that the converted single house would be worth less than the two houses separately. We had to buy the next door house on a buy-to-let mortgage, which had implications for council tax until we had the work done. Then we had to let the council know about the conversion work, as while there was building work ongoing we were eligibile for a reduction in council tax to the buy-to-let property. Then when it was finished we had to have a new mortgage for the whole converted property. We lost a lot of housing equity by doing this, but it was our choice to have the home we want - after all, equity's only useful if you are thinking of selling, right?
Then we had to get the new single house rebanded for Council Tax.
We also had to cut off the utilities on one side and connect everything to the other side. This went as far as having to have the gas pipe cut off under the ground outside the house, as they wouldn't let us leave it, and we had to pay something not too large for this work. The electricity meter is still there, even though disconnected, and to this day E-On still send us a bill for £0 every year for that side of the property!
Due to the remortgaging and losing equity we now have ages left on our mortgage term and very little equity so we can't move to a better mortgage deal which is a bit tough. But on the plus side, we made our dream home. We liked where we lived, we love our neighbours, we didn't want to move but our house was too small. Now it's bigger, and beautiful. It's a 5 bed house but if ever we were to sell we wouldn't get that big a price because it's an end of terrace, no drive way, garages in a separate block etc - things you would otherwise normally have in a 5-bed. It was a real headache but definitely worth it !