yes
at the opposite end to the TRV is another valve. It is called a lockshield valve because it is supposed to have a screw-on cover which prevents you fiddling with it. If you take this off (usually a screw in the middle of the top, and then the plastic dome lifts off) you will find a spindle which can be turned to open or close the valve.
This valve ought to have been adjusted so it is almost closed, usually less than a full turn open from the fully closed position. You can turn it with a new knob, or with a very small adjustable spanner. You can buy replacement universal radiator valve knobs at DIY sheds and plumbers merchant, the fitting will vary according to the make, but the universal ones usually contain a selection of fittings. If you are using an adjustable spanner, make it a very tight fit or you will burr and round off the brass spindle.
If the valves are very old, they might leak round the spindle when disturbed. If so, winding them down to the fully closed or the fully open position will usually stop it. Have some kitchen roll and old towels handy just in case. Water in radiators (unless they are very new, or have been religiously treated with corrosion inhibitor,) will be black with iron oxide, as a result of the steel rads corroding. This will stain carpets and ceilings and is pretty well impossible to remove, so take it seriously. if the valves are less than ten years old, they ought not to leak. If they are 30 years old they almost certainly will.
As for your TRVs, if they are a major brand, you can probably still buy replacement thermostatic heads to fit. Top brands are Pegler, Danfoss and Drayton. The head can be removed by unscrewing a large horizontal nut or knurled ring below the head. No water comes out. However, due to volumes of sales, a replacement head will probably cost more than a complete new valve. However it is much more work to change the complete valve and you will be letting water out. If you have more than two or three to change, a plumber will probably drain the entire system, and do a houseful in a working day. In this case you might as well renew all the lockshields and the bleeding nipples as well, and give the system a chemical clean before draining. If you are fond of DIY and can do basic plumbing you can do all this yourself, but you need enough skill to do it without any leaks, and a few tools.
If you have to buy new valves, the Danfoss RAS-D2 (or C2, bit cheaper) is probably the best on the market. The Drayton TRV4 used to be the best, but is not quite as good. The Danfoss lockshield is also very small and neat, and high quality. Pegler Terrier is a high-quality brand but IMO not so stylish.