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I'm pretty sure that the EL Illuminator should go on after moisturiser. Sort of like a primer. In the interest if research for MN I have just put a bit on under moisturiser and it doesn't look as good.
I think it's pretty pricey for a primer/illuminator so that defines it as a serum for me and I'll keep it going on under. My priority is slowly fading my small age spot and preventing new ones rather than general brightening.