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Aveda is eco friendly but not non toxic, basically they are good for the environment in that they use wind power and use sustainable ingeredients etc but they have sls etc in their products so not good for your skin/body.
I would suggest buying nothing off the highstreet and don't go for something because it says organic on it, read the ingredients and avoid sls, sles, parabens and sulphates, which are the main ones but anything too chemically sounding or a very long ingredient list is generally not good. If you google cosmetic database you can get a better idea of what everthing is, site isn't working for me right now though.
I can recommend lavera as a good, well priced product that is sls free, they do a basis range which is even gentler. I prefer their 'normal' stuff but don't have skin issues to consider. Lucy rose is a really good site because the delivery is free so it's easy to see the price of the products. They sell weleda and green people too which are also good. You can also pick some free samples to try.
The Rainforest Shine range at Body Shop is free of SLS, Parabens etc. Link HERE to one variety, but there are more. I've not used it, but I have used the sister range of Shower Gels which really does not irritate my eczema.
THIS by Philip Kingsley is what I default to when my scalp flares up. Pricer but just fab. SLS and Paraben free.
I have psoriasis on my scalp. I've found Simples shampoo and conditioner really good for my scalp but my hair never felt properly clean. I had to wash and rinse it twice. I've recently been using Elvive with selenium which is ok but think I'll go back to Simple once the Elvive one has ran out. I might try Weleda or maybe the bidyshop. The Simple shampoo is the only shampoo I have ever used that has made a different to my scalp. I would say that for the 12 months I used it my scalp was flake/itch free.
Holland and Barratt have Dr.Organic. The waitrose baby stuff in the link above is v.good, I'd forgotten we used the shampoo as bubble bath for DD when she had baby eczema (I've never used shampoo on her and she's 6 now).